Permeability alteration due to mineral dissolution in partially saturated fractures

[1] During reactive fluid flow in saturated fractures, the relative rates of dissolved mineral transport and local reactions strongly influence local aperture alterations and the resulting changes in fracture permeability (or transmissivity). In the presence of an entrapped residual nonaqueous phase (e.g., CO2 or oil), the spatial distribution of the entrapped phase will influence flow and transport and thus, local aperture alterations. These aperture alterations will in turn alter the balance of forces acting on immobile regions of the trapped phase. The resulting mobilization of the entrapped phase may subsequently alter flow pathways and fracture transmissivity in a manner that defies quantification with currently used constitutive relationships. I present results from quantitative visualization experiments in which fracture aperture and entrapped phase distribution were directly measured at high spatial resolution (75 × 75 mm) during reactive fluid flow. The experiments differed only in the orientation of the fracture with respect to gravity, which influenced both the initial entrapped phase geometry and the evolution of the entrapped phase as dissolution altered fracture apertures. The presence of the entrapped phase leads to a much earlier formation of distinct dissolution channels than has been observed in saturated fractures. Compared to a similar experiment in a fully saturated fracture, dissolution in the partially saturated fractures leads to as much as a 6‐fold increase in transmissivity after an equal amount of dissolution from the fracture surface (doubling of the mean fracture aperture). Furthermore, the relative influence of gravity determines whether trapped bubbles mobilize because of capillary forces (against prevailing viscous forces) or gravitational forces, which is in the direction of prevailing viscous forces for the experiments presented here.